Hydrogen Generation based on Chemical Reaction and its Application
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Abstract
In recent years, the effects of global warming due to CO2 emissions have become serious. Since internal combustion engines (ICEs) where gasoline or diesel are used as fuel release huge amount of CO2, attentions have been paid to the new decarbonization countermeasures of Ices. Among them, H2 is regarded as a kind of eco-friendly fuel not only for fuel cell but also for Ices. So far, we have modified a gasoline electric power generator for using H2 as fuel by amounting a surge tank with a special intaking flow system. Though many useful results have been obtained, problems such as H2 supply method for on-site operation or backfire phenomenon at high load still remain. Therefore, in current paper, in order to deal with the above-mentioned problems. Firstly, H2 generation method based on chemical reaction for onsite operation is suggested and verified. Secondly, a new intake flow system for stable operation was designed and manufactured based on simulation and engine performance test was experimentally investigated. Finally, engine operation test using H2 generated by chemical reaction on-site was conducted. As a result, the maximum H2 generation was 29.3 L/min, and the error from the theoretical value was 2.4 %. In engine performance test for new Intaking flow system, the maxi mum output was 900 W, and the thermal efficiency was 19.0%. In engine operation testing generated H2 on-site, the engine speed decreased by up to 900 rpm compared to compressed H2.
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This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
References
BP plc. Statistical review of world energy 2022 [Internet]. London: BP; 2022 [cited 2023 Oct 5]. Available from: https://www.bp.com/content/dam/bp/business-sites/en/global/corporate/pdfs/energy-economics/statisti cal-review/bp-stats-review-2022-full-report.pdf
IPCC. Sixth assessment report [Internet]. Japan: Ministry of the Environment; 2023 [cited 2023 Oct 5]. Available from: https://www.env.go.jp/earth/ipcc/6th/index.html (In Japanese)
Global Warming Prevention Headquarters. NDC [Internet]. Japan; 2021 [cited 2023 Oct 5]. Available from: https://www.kantei.go.jp/jp/singi/ondanka/kaisai/dai48/pdf/ndc_kouken.pdf (In Japanese)
Yamane K. Recent technology and prospect of reciprocating hydrogen Fuelled engines. Hydrogen Energy System. 2006;31(1):12-19. (In Japanese)
Kensyukan. Hydrogen production technology [Internet]. Japan: Independent Administrative Agency; 2006 [cited 2024 Jan 30]. Available from: https://www.inpit.go.jp/blob/katsuyo/pdf/chart/fippan20.pdf (In Japanese)
Abe I. Hydrogen production by water electrolysis. Hydrogen Energy System. 2008;33(1):19-26. (In Japanese)
Murooka S, Tomoda K, Hoshi N, Cao M, Yoshizaki A, Hirata K. Validity verification of sodium borohydride as fuel for fuel cell electric vehicle. IEEJ Trans Ind Appl. 2012;132(2):299-300. (In Japanese)
Suekawa T, Nitta H, Goto Y, Hoshi N, Fukuda K. Comparison of Volumetric Energy Densities of Hydrogen Reactors for Hydrogen Power Generation Systems Fueled by NaBH4. Journal of the Japan Institute of Power Electronics. 2020;46:124. (In Japanese)
Sian FJ. Development of small hydrogen engine generator [Thesis]. Japan: Shizuoka Institute of Science and Technology; 2021. (In Japanese)
Showa Chemical Co Ltd. Sodium Borohydride [Internet]. Japan: Showa Chemical Co Ltd; 2020 [cited 2023 Oct 5]. Available from: http://www.st.rim.or.jp/~shw/MSDS/19263350.pdf (In Japanese)
Showa Chemical Co Ltd. Citric Acid Anhydride [Internet]. Japan: Showa Chemical Co Ltd; 2023 [cited 2023 Oct 5]. Available from: http://www.st.rim.or.jp/~shw/MSDS/03312250.pdf (In Japanese)
Yoshizaki A. Method and device for producing sodium borohydride [Internet]. Japan: Google; 2015 [cited 2023 Oct 5]. Available from: https://patents.google.com/patent/WO2015190403A1/ja (In Japanese)
Ishizuka K. Research on small reactor for emergency hydrogen generator using sodium borohydride and citric acid [Thesis]. Japan: Tokyo University of Science; 2018. (In Japanese)
WELCO Co Ltd. WPX1 Peristaltic pump [Internet]. Japan: WELCO Co Ltd; 2023 [cited 2023 Oct 5]. Available from: https://www.welco-web.co.jp/product/tubepump/wpx1.html (In Japanese)