การเพิ่มสมบัติเชิงกลและการต้านทานรังสียูวีของวัสดุเชิงประกอบยางธรรมชาติผสมนาโนไทเทเนียมไดออกไซด์
Keywords:
natural rubber, composite, nano-titanium dioxide, UV, agingAbstract
The purpose of this research was to study the influence of adding titanium dioxide nanoparticles on the mechanical properties of natural rubber under UV radiation. The composite was prepared by mixing natural rubber with titanium dioxide nanoparticles at quantities 0, 1, 2, 3, and 4 phr in a two-roll rubber mill. The composites were molded using a compression molding machine, and tensile strength tests were conducted along with morphological studies. The morphological properties observed using a scanning electron microscope revealed that the titanium dioxide nanoparticles were well dispersed, leading to improved mechanical properties with increasing amounts of titanium dioxide nanoparticles. Optical microscope showed the crack patterns of the composite material between titanium dioxide nanoparticles and natural rubber after UV exposure for 30 days at 0, 1, 2, 3, and 4 phr. The results indicated that the cracks on the natural rubber surface decreased as the amount of titanium dioxide nanoparticles increased.
References
Rubbercenter and Technology Co., Ltd. Rubber [Internet]. [updated 2022 May 26; cited 2022 Jul 19]. Available from: https://www.rubbercenter.co.th/content/27439. (In Thai)
Findik F, Yilmaz Y, Köksal T. Investigation of mechanical and physical properties of several industrial rubbers. Materials and Design 2004;25(4):269-76.
Phoempoon P. Carbon nanotubes-rubber blend (natural rubber-styrenebutadiene rubber) composite [thesis]. Songkhla, Thailand: Prince of Songkla University; 2009. (In Thai)
Hayeemasae N, Surya I, Ismail H. Morphology and thermal stability of nano titanium dioxide filled natural rubber prepared by latex mixing method. IOP Conference Series: Materials Science and Engineering 2018;309:012110. doi: 10.1088/1757-899X/309/1/012110.
Aiemsaard P. The modification of amorphous TiO2 surface for the color retention of lake pigment [thesis]. Nakhon Pathom, Thailand: Silpakorn University; 2016. (In Thai)
Sikong L. Titaniun dioxide photocatalyst. Songkhla: C.P. Printing; 2017. (In Thai)
Kongsong P, Phoempoon P, Masae M. Photocatalytic efficiency of potassium doped TiO2 nanowire-nanoparticle hetero-structured films coated on glass substrate under visible light irradiation. Journal of Materials Science and Applied Energy 2018;7(2):300-6.
Masae M, Sririkun W, Kongsong P. Enhancement of band gap and electrical conductivity properties of TiO2 nanowire by Ni with hydrothermal method. Journal of Materials Science and Applied Energy 2022;11(1):1-8.
Kongsong P, Jantaporn W, Masae M. Enhanced photocatalytic activity of Ni doped TiO2 nanowire–nanoparticle hetero–structured films prepared by hydrothermal and sol–gel methods. Surface and Interface Analysis 2020;52(8):486-92.
Mehraz S, Kongsong P, Taleb A. Dokhane N. Sikong L. Large scale and facile synthesis of Sn doped TiO2 aggregates using hydrothermal synthesis. Solar Energy Materials and Solar Cells 2019;189:254-62.
Kongsong P, Taleb A, Masae M, Jeenarong A, Hansud P, Khumruean S. Effect of nitrogen doping on the photocatalytic activity and hydrophobic property of rutile TiO2 nanorods array. Surface and Interface Analysis 2018;50(12-13):1271-7.
Zhang H, Yang H. Shentu B. Chen S. Chen M. Effect of titanium dioxide on the UV-C ageing behavior of silicone rubber. Journal of Applied Polymer Science 2018;135(14):46099-106.
Seentrakoon B, Junhasavasdikul B, Chavasiri W. Enhanced UV-protection and antibacterial properties of natural rubber/rutile-TiO2 nanocomposites. Polymer Degradation and Stability 2013;98(2):566-78.
Thammachot N. Engineering materials. Bangkok, Thailand: SE-Education; 2015. (In Thai)
Zhang H, Yang H, Shentu B. Effect of surface modification of titanium dioxide on the UV‐C aging behavior of silicone rubber. Journal of Applied Polymer Science 2019;136(10):47170-80.
Noman MT, Ashraf MA, Ali A. Synthesis and applications of nano-TiO2. Environmental Science and Pollution Research 2019;26:3262-91.
Mhadhbi M, Abderazzak H, Avar B. Synthesis and properties of Titanium Dioxide nanoparticles [Internet]. Updates on Titanium Dioxide. IntechOpen; 2023. Available from: http://dx.doi.org/10.5772/intechopen.111577.
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