การสังเคราะห์จุลผลึกเซลลูโลสจากต้นธูปฤาษี
Keywords:
Microcrystalline cellulose, Typha angustifolia L., Agricultural residuesAbstract
The objectives of this study were to analyze the use of microcrystalline cellulose extracted from Typha angustifolia L. trees obtained from Songkhla province. Microcrystalline cellulose was extracted from Typha angustifolia L. trees via hydrolysis treatment using sulfuric acid (H2SO4). The study found the Cellulose, Lignin, and Hemicelluloses to be 75.47, 8.33, and 9.40 %, respectively. The morphology of the microcrystalline cellulose was characterized using a field emission scanning electron microscope (FESEM). The result of the physical properties showed a microcrystalline cellulose fiber length of up to 230 micrometers. Fourier-Transform Infrared spectroscopy (FTIR) was used to identify the chemical composition and X-ray diffraction analysis (XRD) showed crystallinity microcrystalline cellulose appearing at peaks 16, 22, and 35 degrees in relation to the plane (101), (101), and (002), respectively. The thermal stability was investigated using the thermogravimetric analysis (TGA) method displayed the decomposition of carbon in the cellulose structure. The detergent method result showed that Typha angustifolia L compound produced a high content of phase cellulose of up to 75 %.
References
Trache D, Hussin MH, Chuin CT, Sabar S, Fazita MN, Taiwo OF, et al. Microcrystalline cellulose: Isolation, characterization and bio-composites application-a review. International Journal of Biological Macromolecules 2016;93:789-804.
Sheltami RM, Abdullah I, Ahmad I, Dufresne A, Kargarzadeh H. Extraction of cellulose nanocrystals from mengkuang leaves (Pandanus tectorius). Carbohydrate Polymers 2012;88(2):772-9.
Zuluaga R, Putaux JL, Cruz J, Vélez J, Mondragon I, Gañán P. Cellulose microfibrils from banana rachis: Effect of alkaline treatments on structural and morphological features. Carbohydrate Polymers 2009;76(1):51-9.
Johar N, Ahmad I, Dufresne A. Extraction, preparation and characterization of cellulose fibres and nanocrystals from rice husk. Industrial Crops and Products 2012;37(1):93-9.
Kanokpanont S, Inthaphunt S, Bunsiri A. Synthesis of carboxymethyl cellulose from young coconut husk. Songklanakarin Journal of Plant Science 2017;4(4):60-5.
Šturcová A, Davies GR, Eichhorn SJ. Elastic modulus and stress-transfer properties of tunicate cellulose whiskers. Biomacromolecules 2005;6(2):1055-61.
Silvério HA, Neto WPF, Dantas NO, Pasquini D. Extraction and characterization of cellulose nanocrystals from corncob for application as reinforcing agent in nanocomposites. Industrial crops and products 2013;44:427-36.
Barragán EUP, Guerrero CFC, Zamudio AM, Cepeda ABM, Heinze T, Koschella A. Isolation of cellulose nanocrystals from Typha domingensis named southern cattail using a batch reactor. Fibers and Polymers 2019;20(6):1136-44.
Rosa MF, Medeiros ES, Malmonge JA, Gregorski KS, Wood DF, Mattoso LHC, Glenn G, Orts WJ, Imam SH. Cellulose nanowhiskers from coconut husk fibers: Effect of preparation conditions on their thermal and morphological behavior. Carbohydrate Polymers 2010;81(1):83-92.
Kargarzadeh H, Ahmad I, Abdullah I, Dufresne A, Zainudin SY, Sheltami RM. Effects of hydrolysis conditions on the morphology, crystallinity, and thermal stability of cellulose nanocrystals extracted from kenaf bast fibers. Cellulose 2012;19(3):855-66.
Samitinand T. Thai Plant Names, The Forest Herbarium. Royal Forest Dept. Bangkok, Thailand; 2001.
El-Sakhawy M, Hassan ML. Physical and mechanical properties of microcrystalline cellulose prepared from agricultural residues. Carbohydrate Polymers 2007;67(1):1-10.
Agblevor FA, Ibrahim MM, El-Zawawy WK. Coupled acid and enzyme mediated production of microcrystalline cellulose from corn cob and cotton gin waste. Cellulose 2007;14(3):247-56.
El-Naggar ME, Shaarawy S, Hebeish A. Bactericidal finishing of loomstate, scoured and bleached cotton fibres via sustainable in-situ synthesis of silver nanoparticles. International Journal of Biological Macromolecules 2018;106:1192-202.
Pasta PC, Silva AC, Jorgetto AO, Saeki MJ, Pedrosa VDA, Martines MA, Schneider JF, et al. Use of Typha angustifolia L. as biosorbent to remove chloramphenicol in aqueous samples. European Journal of Advanced Chemistry Research 2022;3(1):64-86.
Brown R. Biochar production technology. In: Lehmann J, Joseph S, editors. Biochar for environmental management: Science and technology. London: Earthscan; 2010. p.127-46.
Li H, Qu Y, Xu J. Microwave-assisted conversion of lignin. In: Fang Z, Smith, Jr. RL, Qi X, editors. Production of biofuels and chemicals with microwave. Dordrecht, Netherlands: Springer; 2015. p. 61-82.
Downloads
Published
Issue
Section
License
Copyright (c) 2022 Kasem Bundit University
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
*Copyright
The article has been published in Kasem Bundit Engineering Journal (KBEJ) is the copyright of the Kasem Bundit University. Do not bring all of the messages or republished except permission from the university.
* Responsibility
If the article is published as an article that infringes the copyright or has the wrong content the author of article must be responsible.
