INFLUENCE OF ACETIC ACID ON COLD SINTERING OF ZIRCONIA CERAMICS

Authors

  • Pongsakorn Kunakul Program of Materials Innovation, Faculty of Science, Maejo University
  • Chokchai Yatongchai Program of Materials Innovation, Faculty of Science, Maejo University

Keywords:

Zirconia, Cold sintering process, Acetic acid, Density, Mechanical properties

Abstract

This study investigates the influence of acetic acid on the cold sintering process; CSP of zirconia ceramics; ZrO2. Zirconia powders were treated with acetic acid solutions at various concentrations (0.10, 1, and 17.45 M), and the effects on relative density, porosity, microstructure, and mechanical properties of the sintered samples were examined after sintering at temperatures ranging from 600 to 1,200°C for different durations. The results showed that the addition of acetic acid significantly improved the relative density and reduced the porosity of zirconia ceramics. Furthermore, improvements in microstructure and microhardness were observed with increasing acid concentration and sintering time. This study highlights the potential of acetic acid as a transient solvent to enhance the cold sintering of zirconia ceramics at low temperatures, offering a promising route for energy-efficient and environmentally friendly ceramic fabrication.

References

Abd El-Ghany, O.S., & Sherief, A.H. (2016). Zirconia based ceramics, some clinical and biological aspects: Review. Future Dental Journal, 2(2), 55-64.

Bartoletti, A., Mercadelli, E., Gondolini, A., & Sanson, A. (2024). Exploring the Potential of Cold Sintering for Proton-Conducting Ceramics: A Review. Materials, 17(20), 5116.

Funahashi, S., Guo, J., Guo, H., Wang, K., Baker, A.L., Shiratsuyu, K., & Randall, C.A. (2017). Demonstration of the cold sintering process study for the densification and grain growth of ZnO ceramics. Journal of the American Ceramic Society, 100(2), 546-553.

Gong, Y., Xu, H., Zhu, G., Jiang, X., Wei, T., Long, S., & Zhao, Y. (2023). Preparation and properties of LiF transparent ceramics by cold sintering process. Ceramics International, 49(12), 20298-20303.

Guo, H., Bayer, T.J.M., Guo, J., Baker, A., & Randall, C.A. (2017). Cold sintering process for 8 mol%Y2O3-stabilized ZrO2 ceramics. Journal of the European Ceramic Society, 37(5), 2303-2308.

Guo, H., Guo, J., Baker, A., & Randall, C.A. (2017). Cold sintering process for ZrO2-based ceramics: significantly enhanced densification evolution in yttria-doped ZrO2. Journal of the American Ceramic Society, 100(2), 491-495.

Guo, J., Guo, H., Baker, A.L., Lanagan, M.T., Kupp, E.R., Messing, G.L., & Randall, C.A. (2016). Cold Sintering: A Paradigm Shift for Processing and Integration of Ceramics. Angewandte Chemie International Edition, 55(38), 11457-11461.

Guo, N., Zhu, G., Xu, H., Jiang, X., Zhang, X., Song, J., & Yu, A. (2022). Preparation of CaF2transparent ceramics by cold sintering. Ceramics International, 48(23, Part A), 34184-34189.

Jabr, A., Fanghanel, J., Fan, Z., Bermejo, R., & Randall, C. (2023). The effect of liquid phase chemistry on the densification and strength of cold sintered ZnO. Journal of the European Ceramic Society, 43(4), 1531-1541.

Kelly, J.R., & Denry, I. (2008). Stabilized zirconia as a structural ceramic: An overview. Dental Materials, 24(3), 289-298.

Kumar, M., Ben Achour, M.A., Lasgorceix, M., Quadros, P., Mincheva, R., Raquez, J.-M., & Leriche, A. (2024). Densification of hydroxyapatite through cold sintering process: Role of liquid phase chemistry and physical characteristic of HA powder. Open Ceramics, 17, 100566.

Tosoni, S., & Pacchioni, G. (2016). Acetic acid ketonization on tetragonal zirconia: Role of surface reduction. Journal of Catalysis, 344, 465-473.

Zhou, M.F., Hu, C.C., Yin, J.B., Jiang, Y., Liu, B., & Song, K.X. (2022). Cold sintering optimized SrF2 microwave dielectric ceramics for the development of dielectric resonator antenna at 5G millimeter-wave band. Ceramics International, 48(20), 29847-29853.

Downloads

Published

2026-08-28

How to Cite

Kunakul, P., & Yatongchai, C. (2026). INFLUENCE OF ACETIC ACID ON COLD SINTERING OF ZIRCONIA CERAMICS . PSRU Journal of Science and Technology, 11(2), 122–134. retrieved from https://ph01.tci-thaijo.org/index.php/Scipsru/article/view/262332

Issue

Section

Research Articles