Efficiency of Cathode Catalyst Between Ag/C and AgMnxOy/C for Glucose Membraneless Alkaline Fuel Cell

Main Article Content

Chakkrapong Chaiburi
Kantrakorn Suwanraksa
Sitanan Bunyord

Abstract

This research aims to analyse and develop catalysts for use in membraneless alkaline glucose solution fuel cells. Glucose solution is a polyalcohol group. Glucose solution can be developed for use in oxidation reactions. The advantage of glucose solution is that it is a form of renewable energy, contributing to its suitability for alkaline fuel cells. Catalysts for cathode electrodes for use in membraneless glucose solution fuel cells are studied in this research. The AgMnxOy/C catalyst is resistant to the oxidation of glucose solution. After doping with glucose solution fuel, it is possible to test the electricity generation efficiency of alkaline fuel cells using glucose solution fuel at a concentration of 0.1 M. For the anode electrode, the catalytic performance of PdNi/C was further improved by synthesising Ni with Pd in a 1:1 atomic ratio. The experimental results involve a direct glucose membraneless alkaline fuel cell (DGMAFC). Using the PdNi/C anode and the AgMnxOy/C cathode showed a higher power density of about 77.30 % than using the PdNi/C anode and the Ag/C cathode. Therefore, selection of glucose solution can be developed for renewable energy to increase energy. It is then necessary to study physical characteristics such as the alloy ratio and to study the electro-oxidation-reduction reactions of catalysts using scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and cyclic voltammetry (CV).

Article Details

How to Cite
1.
Chaiburi C, Suwanraksa K, Bunyord S. Efficiency of Cathode Catalyst Between Ag/C and AgMnxOy/C for Glucose Membraneless Alkaline Fuel Cell. J Appl Res Sci Tech [Internet]. 2022 Dec. 19 [cited 2024 May 14];21(2):126-3. Available from: https://ph01.tci-thaijo.org/index.php/rmutt-journal/article/view/249657
Section
Research Articles

References

Karim NA, Kamarudin SK. An overview on non-platinum cathode catalysts for direct methanol fuel cell. Appl Energ. 2013;103:

-20.

Ren X, Lv Q, Liu L, Liu B, Wang Y, Liu A, et al. Current progress of Pt and Pt-base electrocatalysts used for fuel cells. Sustain Energy Fuels. 2020;4(1):15-30.

Chen J, Zheng H, Kang J, Yang F, Cao Y. Xiang M. An alkaline direct oxidation glucose fuel cell using three-dimensional structural Au/Ni-foam as catalytic electrodes. RSC Adv. 2017;7(5):3035-42.

Chen J, Zhao CX, Zhi MM, Wang K, Deng L, Xu G. Alkaline direct oxidation glucose fuel cell system using silver/nickel foams as electrodes. Electrochimica Acta. 2012;66:133-38.

Han XJ, Sun PX, Pan WJ, Chen LJ, Chen ZJ, Zhang Q, et al. Porous multi-layer MoO2/-MnO2 composite cathode for phosphorylated glucose fuel cell. J Solid State Electr. 2021;25(6):1861-69.

Valim RB, Santos MC, Lanza MRV, Machado SAS, Lima FHB, Calegaro ML. Oxygen reduction reaction catalyzed by ε-MnO2: Influence of the crystalline structure on the reaction mechanism. Electrochimica Acta. 2012;85:423–31.

Selvakumar K, Kumar SMS, Thangamuthu R, Ganesan K, Murugan P, Rajput P, et al. Physiochemical investigation of shape-designed MnO2 nanostructures and their influence on oxygen reduction reaction activity in alkaline solution. J Phys Chem C. 2015;119:6604–18.

Sun W, Hsu A, Chen R. Carbon-supported tetragonal MnOOH catalysts for oxygen reduction reaction in alkaline media. J Power Sources. 2011;196:627–35.

Calegaro ML, Lima FHB, Ticianelli EA. Oxygen reduction reaction on nanosized manganese oxide particles dispersed on carbon in alkaline solutions. J Power Sources. 2006;158:735–39.

Laiwan P, Therdthianwong A, Therdthianwong S. Influence of carbon support type and metal adsorption time on performance of Pd/C catalyst for ethanol electro-oxidation in alkaline: The 54th Kasetsart University Annual Conference; 2016February2-5. Bangkok. Thailand.

Lu Y, Wang Y, Chen W. Silver nanorods for oxygen reduction: Strong effects of protecting ligand on the electrocatalytic activity. J Power Sources. 2011;196(6):3033–38.

Kostowskyj MA, Kirk D, Thorpe S. Ag and Ag–Mn nanowire catalysts for alkaline fuel cells. Int J Hydrog Energy. 2010;35:5666–72.