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In this work, poly(methyl methacrylate-acrylic acid-divinyl benzene) (P(MMA-AA-DVB)) microcapsules encapsulating both bismuth vanadate (BiVO4) and magnetite (Fe3O4) nanoparticles were prepared by microsuspension iodine transfer polymerization for the treatment of dyes in wastewater. The colloidal stable spherical microcapsules with high encapsulation efficiency were produced. The extraction of PMMA segment in polymer microcapsule shell using various solvents was carried out to increase the porosity of polymer shell leading to the increase of dye and encapsulated nanoparticle interaction. It was found that using polymer microcapsules at 0.5 wt% of acetone as a solvent presented the highest dye removal efficiency equal to that of pristine BiVO4 nanoparticles. The dye removal efficacy of the microcapsules was gradually reduced when they were reused for 5 times. However, the treatment efficiency was still higher than 50 %. Therefore, the obtained P(MMA-AA-DVB) microcapsules exhibited high performance for dye treatment in wastewater.
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Mahato N, Sharma K, Sinha M, Baral ER, Koteswararao R, Dhyani A, et al. Bio-sorbents, industrially important chemicals and novel materials from citrus processing waste as a sustainable and renewable Bioresource: A review. J Adv Res. 2020;23:61-82
Hepel M, Hazelton S. Photoelectrocatalytic degradation of diazo dyes on nanostructured WO3electrodes. Electrochimica Acta. 2005;50(25-26):5278-91.
Zheng Q, Lee C. Visible light photoelectrocatalytic degradation of methyl orange using anodized nanoporous WO3. Electrochim. Acta. 2014;115:140-5.
Kim C, Kim JT, Kim KS, Jeong S, Kim HY, Han YS. Immobilization of TiO2 on an ITO substrate to facilitate the photoelectrochemical degradation of an organic dye pollutant. Electrochim. Acta. 2009;54(24):5715-20.
Yin W, Wang W, Zhou L, Sun S, Zhang L. CTAB-assisted synthesis of monoclinic BiVO4 photocatalyst and its highly efficient degradation of organic dye under visible-light irradiation. J Hazard Mater. 2010;173(1-3):194-9.
Sun M, Guo P, Wang M, Ren F. The effect of pH on the photocatalytic performance of BiVO4 for phenol mine sewage degradation under visible light. Optik. 2019;179:672-9.
Fernández-Domene RM, Sánchez-Tovar R, Lucas-Granados B, Muñoz-Portero M-J, Ramírez-Grau R, Garcia-Anton J. Visible-light photoelectrodegradation of diuron on WO3 nanostructures. J Environ Manage. 2018;226:249-55.
Forgacs E, Cserhati T, Oros G. Removal of synthetic dyes from wastewaters: a review. Environment international. 2004;30(7):953-71.
Akpan UG, Hameed BH. Parameters affecting the photocatalytic degradation of dyes using TiO2-based photocatalysts: a review. J Hazard Mater. 2009;170(2-3):520-9.
Chatchai P, Murakami Y, Kishioka S-y, Nosaka AY, Nosaka Y. Efficient photocatalytic activity of water oxidation over WO3/BiVO4 composite under visible light irradiation. Electrochim. Acta. 2009;54(3):1147-52.
Chatchai P, Nosaka AY, Nosaka Y. Photoelectrocatalytic performance of WO3/BiVO4 toward the dye degradation. Electrochim. Acta.2013;94:314-9.
Chatchai P, Kishioka S-y, Murakami Y, Nosaka AY, Nosaka Y. Enhanced photoelectrocatalytic activity of FTO/WO3/BiVO4 electrode modified with gold nanoparticles for water oxidation under visible light irradiation. Electrochim. Acta. 2010;55(3):592-6.
Chaiyasat P, Noppalit S, Okubo M, Chaiyasat A. Innovative synthesis of high performance poly (methyl methacrylate) microcapsules with encapsulated heat storage material by microsuspension iodine transfer polymerization (ms ITP). Sol Energy Mater Sol Cells. 2016;157:996-1003 :996-1003.
Chaiyasat P, Noppalit S, Okubo M, Chaiyasat A. Do encapsulated heat storage materials really retain their original thermal properties. Phys Chem Chem Phys.. 2015;17(2):1053-9.
Jantang S, Chaiyasat P. High Performance Poly (methyl methacrylate-acrylic acid-divinylbenzene) Microcapsule Encapsulated Heat Storage Material for Thermoregulating Textiles. Fibers Polym. 2018; 19(10): 2039-48.
Okunaka S, Tokudome H, Hitomi Y, Abe R. Preparation of fine particles of sheelite-monoclinic phase BiVO4 via an aqueous chelating method for efficient photocatalytic oxygen evolution under visible-light irradiation. J Mater Chem A. 2016;4(10):3926-32.
Tomovska R, Daniloska V, Asua JM. Surface modification of TiO2 nanoparticles via photocataliticaly induced reaction: Influence of functionality of silane coupling agent. Appl Surf Sci. 2013;264:670-3.
Zhao J, Milanova M, Warmoeskerken MM, Dutschk V. Surface modification of TiO2 nanoparticles with silane coupling agents. Colloids Surf A. 2012;413:273-9.
Moghaddam E, Youzbashi A, Kazemzadeh A, Eshraghi M. Photoluminescence investigation of ZnO quantum dots surface modified with silane coupling agent as a capping agent. J Lumin. 2015;168:158-62.
Xie Y, Hill CA, Xiao Z, Militz H, Mai C. Silane coupling agents used for natural fiber/polymer composites: A review. Composites Part A. 2010;41(7):806-19.
Tangsongcharoen W, Punyamoonwongsa P, Chaiyasat P. High performance biocompatible cellulose‐based microcapsules encapsulating gallic acid prepared by inverse microsuspension polymerization. Polymer International. 2019;68(4):714-23.
Sadchaiyaphum J, Phapugrangkul P, Chaiyasat P, Chaiyasat A. High Encapsulation Efficiency of Magnetite Nanoparticles in Hydrophobic Polymer Microcapsules using Microsuspension Conventional Radical Polymerization. Orient J Chem. 2019;35(2):516-22.
Shi Y, Hu Y, Zhang L, Yang Z, Zhang Q, Cui H, et al. Palygorskite supported BiVO4 photocatalyst for tetracycline hydrochloride removal. Appl Clay Sci. 2017;137:249-58.
Ke D, Peng T, Ma L, Cai P, Dai K. Effects of hydrothermal temperature on the microstructures of BiVO4 and its photocatalytic O2 evolution activity under visible light. Inorganic Chemistry. 2009;48(11):4685-91.
Chaiyasat P, Islam MZ, Chaiyasat A. Preparation of poly (divinylbenzene) microencapsulated octadecane by microsuspension polymerization: oil droplets generated by phase inversion emulsification. RSC Adv. 2013;3(26):10202-7.
Chaiyasat P, Chaiyasat A, Boontung W, Promdsorn S, Thipsit S. Preparation and characterization of poly (divinylbenzene) microcapsules containing octadecane. Mater Sci Appl. 2011;2(08):1007.