Effects of Mn-Doped TiO2 and in Nanoparticles on Melting Point, Printability, and Wettability of SAC305 Lead-Free Solder Paste

Authors

  • วันยุทธ สุวรรณเครือ
  • ประธาน บุรณศิริ
  • กรรณชัย กัลยาศิริ

Keywords:

Lead-free solder, Nanoparticle, Wettability, Printability

Abstract

Effects of Mn-doped TiO2 and In nanoparticles on melting point, printability, and wettability of SAC305 lead-free solder pastes on Cu substrate were investigated in this paper. The composite solders were divided into two groups. The first one was prepared by adding 0.05, 0.1, 0.5, and 1.0 wt% of Mn-doped TiO2 and the second one was included additional indium of 0.5 wt% to the first group. The melting characteristic of solder was characterized by differential scanning calorimeter (DSC). The printability was measured by the weight ratio of solder, before and after printing the solder on Cu substrate. The solder was reflowed in a reflow oven at 260 oC for 30 seconds. The wettability was investigated in the terms of spread ratio, spread factor, and contact angle. It was found that liquidus temperature and solidus temperature of nano-composite solder were lower than those of SAC305. However, the melting range of nano-composite solder was greater than that of SAC305. The wettability of solder was improved by the addition of small amount of Mn-doped TiO2 and the wettability was then decreased as the amount of Mn-doped TiO2 increased. The addition of indium decreased the wettability of composite solder. The printability of solder was decreased due to the addition of Mn-doped TiO2 and indium.

References

[1] E. Bradley, C. A. Handwerker, J. Bath, R. D. Parker, and R. W. Geaney,“Lead-free electronics iNEMI Projects lead to successful manufacturing,” Wiley-IEEE Press, United State of America, 2007
[2] M. Abtew, and G. Selvaduray,“Lead-free solderin microelectronic,” Materials Science & Engineering R: Reports, vol. 27, pp. 95-141, 2000.
[3] R. Mahmudi, and S. Mahin-Shirazi, “Effect of Sb addition on tensile deformation behavior of lead-free Sn-3.5Ag solder alloy,” Materials and Design, vol. 32, pp. 5027-5032, 2011.
[4] H. Conrad, Z. Guo, Y. Fahmy, and D. I. Yang, “Influence of microstructure size on the plastic deformation kinetics, fatigue crack growth rate, and low-cycle fatigue of solder joint,” Journal of Electronic Materials, vol. 28, pp. 1062-1070, 1999.
[5] J. L. Marshall, J. Calderon, J. Sees, G. Lucey, and J. S. Hwang, “Composite solder,” IEEE Transaction on Components, Hybrids, and Manufacturing Technology, vol. 14, pp. 698-702, 1991.
[6] Z. Moser, P. Sebo, W. Gasior, P. Svec, and J. Pstrus, “Effect of indium on wettability of Sn-Ag-Cu solders,” Experiment vs Modeling Part I, CALPHAD: Computer Coupling of Phase Diagrams and Thermochemistry, vol. 33, pp. 63-68, 2009.
[7] H. S. Betrabet, S. M. McGee, and J. K. McKinlay, “Processing dispersion-strengthened Sn-Pb solder to achieve microstructural refinement and stability,” Scripta Metallurgica et Materialia, vol. 25, pp. 2323-2328, 1991.
[8] H. Mavoori, and S. Jin, “New, creep-resistant, low melting point solder with ultrafine oxide dispersions,” Journal of Electronic Materials, vol. 27, pp. 1216-1222, 1998.
[9] K. Kanlayasiri, T. Ariga, and M. Ongkolwongrojn, “Influence of indium addition on characteristics of Sn-0.3Ag-0.7Cu solder alloy,” Journal of Alloys and Compounds, vol. 485, pp. 225-239, 2009.
[10] S. M. L. Nai, J. Wei, and M. Gupta, “Influence of ceramic reinforcements on the wettability and mechanical properties of novel lead-free solder composites,” Tin Soild Films, vol. 504, pp. 401-404, 2006.
[11] S. M. L. Nai, J. Wei, and M. Gupta, “Improving the performance of lead-free solder reinforced with multi-walled carbon nanotubes,” Materials. Science and Engineering: A, vol. 423, pp.166-169, 2006.
[12] T. B. Massalski, Binary alloy phase diagram, 2nd Edition, ASM International, Materials Park, 1990.
[13] A. J. Boesenberg, I. E. Anderson, and J. L. Harringa, “Development of Sn-Ag-Cu-X solder for electronic assembly by micro-alloying with Al,” Journal of Electronic Materials, vol. 41, pp. 1868-1881, 2012.
[14] R. Ashayer, S. H. Mannan, S. Sajjadi, M.P. Clode, and M. M. Miodownik, “Nanoparticle enhanced solders for high temperature environments,” 9th Electronics packaging technology conference, Singapore, pp. 109-113, 2007.
[15] S. Mallik, N. N. Ekere, R. Durairaj, A. E. Marks, and A. Seman, “Wall-slip effects in SnAgCu solder pastes used in electronics assembly applications,” Materials and Design, vol. 30, pp. 4502-4506, 2009.
[16] J. Liu, Y.L. Gao, and Q. J. Zhai, “Recent development of nano-solder paste for electroincs interconnect applications,” Electronics Packaging Technology Conference, pp. 84-93, 2008.

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Published

2020-06-19

How to Cite

[1]
สุวรรณเครือ ว. . ., บุรณศิริ ป. . ., and กัลยาศิริ ก. . ., “Effects of Mn-Doped TiO2 and in Nanoparticles on Melting Point, Printability, and Wettability of SAC305 Lead-Free Solder Paste ”, Eng. & Technol. Horiz., vol. 33, no. 2, pp. 64–69, Jun. 2020.

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Research Articles