APPLICATION OF POLYDIACETYLENE REAGENTS IN SIMPLE FLOW INJECTION SPECTROPHOTOMETRIC SYSTEM FOR DETERMINATION OF LEAD IONS

Authors

  • Apichart Boonmalai มหาวิทยาลัยราชภัฏนครสวรรค์
  • Thanutpon Pattanatornchai

DOI:

https://doi.org/10.14456/lsej.2021.14

Keywords:

Flow injection, Lead, Polydiacetylene, Surfactant

Abstract

The purpose of this research was to apply polydiacetylenes reagents in a simple flow injection spectrophotometric system for determination of lead ions. The reagent was prepared by mixing of 10,12-pentacosadiynoic acid (PCDA) and sodium dodecyl sulphate (SDS) as ratio 1:5 mol. Then, the mixture forms conjugated polymer upon uv-irradiation. The fresh blue suspension can be used as reagent in the flow injection spectrophotometric system. The experimental conditions were optimized such as concentration of poly(PCDA/SDS), volume of reagent loop, length of mixing coil , flow rate and stop time. The calibration curve was in the range of 0 – 100 ppm. The limit of detection and the limit of quantitation were 0.59 and 1.98 ppm, respectively. The recoveries were in the range of 94.5 – 98.7% and the sample throughput was 27 samples per hour. This technique was found to be good accurate and precision. The propose method was applied to determine amount of lead (Pb2+) in water samples. All results were in good agreement with those obtained from a flame atomic absorption spectroscopy (FAAS) method.

References

Chamjangali MA, Boroumand S, Bagherian G, Goudarzi N. Construction and characterization a non- amalgamation voltammetric flow sensor for online simultaneous determination of lead and cadmium ions. Sensors and Actuators B Chemical 2017;253:124-136.

Dasbasi T, Sacmaci S, Ulgen A, Kartal S. A solid phase extraction procedure for the determination of Cd(II) and Pb(II) ions in food and water samples by flame atomic absorption spectrometry. Food Chem 2015;174:591-596.

Guo J, Yang L, Zhu L, Chen D. Selective detection of metal ions based on nanocrystalline ionochromic polydiacetylene, Polymer 2013;54:743-749.

Kazantzi V, Kabir A, Furton KG, Anthemidis A. Fabric fiber sorbent extraction for on-line toxic metal determination by atomic absorption spectrometry: Determination of lead and cadmium in energy and soft drinks, Microchemical Journal 2018;137:285-291.

Klamtet J, Sanguthai S, Sriprang S. Determination of lead in aqueous samples using a flow injection analysis system with on-line preconcentration and spectrophotometric detection. Nu Science Journal 2007;4(2):122-131.

Kokkinos C, Economou A, Goddard NG, Fielden PR, Baldock SJ. Determination of Pb(II) by sequential injection/ stripping analysis at all-plastic electrochemical fluidic cells with integrated composite Electrodes. Talanta 2016;153:170-176.

Kolling L, Zmozinski AV, Vale MGR, Silva MM. The use of dried matrix spot for determination of Pb and Ni in automotive gasoline by solid sampling high-resolution continuum source graphite furnace atomic absorption spectrometry. Talanta 2019;205:120105.

Lee CG, Kang S, Oh J, Eom MS, Oh J, Kim MG. et al. A colorimetric and fluorescent chemosensor for detection of Hg2+ using counterion exchange of cationic polydiacetylene. Tetrahedron Lett 2017;58:4340-4343.

Li Y, Wang L, Wen Y, Ding B, Sun G, Ke T. et al. Constitution of a visual detection system for lead(II) on polydiacetylene–glycine embedded nanofibrous membranes. Journal of Materials Chemistry A 2015;3:9722-9730.

Milne A, Landing W, Bizimis M, Morton P. Determination of Mn, Fe, Co, Ni, Cu, Zn, Cd and Pb in seawater using high resolution magnetic sector inductively coupled mass spectrometry (HR-ICP-MS). Analytica Chimica Acta 2010;665:200-207.

Narkwiboonwong P, Tumcharern G, Potisatityuenyong A, Wacharasindhu S, Sukwattanasinitt M. Aqueous sols of oligo(ethylene glycol) surface decorated polydiacetylene vesicles for colorimetric detection of Pb2+. Talanta 2011;83:872-878.

O'Sullivan JE, Watson RJ, Butler ECV. An ICP-MS procedure to determine Cd, Co, Cu, Ni, Pb and Zn in oceanic waters using in-line flow-injection with solid-phase extraction for Preconcentration. Talanta 2013;115:999-1010.

Pankaew A, Traiphol N, Traiphol R. Tuning the sensitivity of polydiacetylene-based colorimetric sensors to UV light and cationic surfactant by co-assembling with various polymers. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2021;608(5):125626.

Pattanatornchai T, Boonmalai A. Colorimetric determination of Pb2+ based on ionochromic polydiacetylene/anionic surfactant materials. Key Engineering Materials 2019;824:212-218.

Phonchai N, Khanantong C, Kielar F, Traiphol R, Traiphol N. Enhancing thermal and chemical sensitivity of polydiacetylene colorimetric sensors: The opposite effect of zinc oxide nanoparticles. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2020;589:124459.

Souza JP, Cerveira C, Miceli TM, Moraes DP, Mesko MF, Pereira JSF. Evaluation of sample preparation methods for cereal digestion for subsequent As, Cd, Hg and Pb determination by AAS-based. Food Chemistry 2020;321:126715.

Salido A, Jones BT. Simultaneous determination of Cu, Cd and Pb in drinking-water using W-Coil AAS. Talanta 1999;50(3):649-659.

Wang M, Wang F, Wang Y, Zhang W, Chen X. Polydiacetylene-based sensor for highly sensitive and selective Pb2+ detection. Dyes Pigm 2015;120:307-313.

Downloads

Published

2021-11-04

How to Cite

Boonmalai, A. ., & Pattanatornchai, T. (2021). APPLICATION OF POLYDIACETYLENE REAGENTS IN SIMPLE FLOW INJECTION SPECTROPHOTOMETRIC SYSTEM FOR DETERMINATION OF LEAD IONS . Life Sciences and Environment Journal, 22(2), 274–286. https://doi.org/10.14456/lsej.2021.14

Issue

Section

Research Articles