Characterization of Prussian blue-immobilized chitin-coated nylon fibers as adsorbent for cesium ions
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Published:
Sep 14, 2018
Keywords:
Cesium Chitin-coated nylon fiber Chitosan-coated rayon fiber Prussian blue Adsorption
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Abstract
A Prussian blue (PB; KFe)-immobilized chitin-coated nylon (KFe/CT/nylon) fiber was successfully synthesized for the first time. The characteristics of this fiber were compared to that of a KFe-immobilized chitosan-coated rayon (KFe/CTS/rayon) fiber, which shows excellent cesium ion (Cs+) adsorption and has a high potential for practical use. The aim of producing the KFe/CT/nylon fiber is to study the feasibility of using it instead of a KFe/CTS/rayon fiber to adsorb Cs+ from contaminated water. CT can not only react with KFe but is also cheaper than CTS; therefore, it is interesting to consider KFe/CT/nylon fiber as an alternative material for Cs+ adsorption. The interactions between KFe and CT in the nylon fiber or KFe and CTS in the rayon fiber were confirmed via X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and Fourier transform infrared (FTIR) spectroscopy. The Cs+ concentration was determined using inductively coupled plasma mass spectrometry (ICP-MS). The Cs+ adsorption capacity of the KFe/CTS/rayon and KFe/CT/nylon fibers were compared. The Cs+ adsorption capacity of the KFe/CTS/rayon fiber (90.5%) was found to be significantly higher than that of the KFe/CT/nylon fiber (16.9%) at an initial Cs+ concentration of 0.67 mg/L.
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Dechojarassri, D., Omote, S., Minamino, T., Nishida, K., Furuike, T., & Tamura, H. (2018). Characterization of Prussian blue-immobilized chitin-coated nylon fibers as adsorbent for cesium ions. Engineering and Applied Science Research, 45(3), 196–202. Retrieved from https://ph01.tci-thaijo.org/index.php/easr/article/view/111649
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ORIGINAL RESEARCH
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References
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[26] Guivar JAR, Sanches EA, Bruns F, Sadrollahi E, Morales MA, López EO, Litterst FJ. Vacancy ordered gamma-Fe2O3 nanoparticles functionalized with nanohydroxyapatite: XRD, FTIR, TEM, XPS and Mössbauer studies. Appl Surf Sci. 2016;389:721-34.
[27] Liu H, Wei G, Xu Z, Liu P, Li Y. Quantitative analysis of Fe and Co in co-substituted magnetite using XPS: The application of non-linear least squares fitting (NLLSF). Appl Surf Sci. 2016;389:438-46.
[28] Arun T, Prakash K, Kuppusamy R, Justin Joseyphus R. Magnetic properties of Prussian blue modified Fe3O4 nanocubes. J Phys Chem Solids. 2013;74:1761-8.
[29] Akhtar F, Podder J. A study on growth, structural, optical and electrical characterization of L-alanine single crystal for optoelectronic devices. Res J Phys. 2012;6:31-40.
[30] Shan Y, Yang G, Gong J, Zhang X, Zhu L, Qu L. Prussian blue nanoparticles potentiostatically electrodeposited on indium tin oxide/chitosan nanofibers electrode and their electrocatalysis towards hydrogen peroxide. Electrochim Acta. 2008;53: 7751-5.
[2] Jarai M, Deng Y, Markus F, Harsh JB. Cesium incorporation and diffusion in cancrinite, sodalite, zeolite, and allophane. Micropor Mesopor Mat. 2005;86:277-86.
[3] El-Naggar MR, El-Kamash AM, El-Dessouky MI, Ghonaim AK. Two-step method for preparation of NaA-X zeolite blend from fly ash for removal of cesium ions. J Hazard Mater. 2008;154:963-72.
[4] Munthali MW, Johan E, Aono H, Matsue N. Cs+ and Sr2+ adsorption selectivity of zeolites in relation to radioactive decontamination. J Asian Ceram Soc. 2015;3:245-50.
[5] Mimura H, Yokota K, Akiba K, Onodera Y. Alkali hydrothermal synthesis of zeolites from coal fly ash and their uptake properties of cesium ion. J Nucl Sci Technol. 2001;38:766-72.
[6] Cortés-Martínez R, Olguín MT, Solache-Ríos M. Cesium sorption by clinoptilolite-rich tuffs in batch and fixed-bed systems. Desalination. 2010;258:164-70.
[7] Zhang A, Li Y, Dai Y, Xu L. Development of a new simultaneous separation of cesium and strontium by extraction chromatograph utilization of a hybridized macroporous silica-based functional material. Sep Purif Technol. 2014;127:39-45.
[8] Watari K, Imai K, Ohmomo Y, Muramatsu Y, Nishimura Y, Izawa M, Baciles LR. Simultaneous. Adsorption of Cs-137 and I-131 from water and milk on “metal ferrocyanide-anion exchange resin". J Nucl Sci Technol. 1988;25:495-9.
[9] Valsala TP, Roy SC, Shah JG, Gabriel J, Raj K, Venugopal V. Removal of radioactive caesium from low level radioactive waste (LLW) streams using cobalt ferrocyanide impregnated organic anion exchanger. J Hazard Mater. 2009;166:1148-53.
[10] Ishihara R, Fujiwara K, Harayama T, Okamura Y, Uchiyama S, Sugiyama M, Someya T, Amakai W, Umino S, Ono T, Nide A, Hirayama Y, Baba T, Kojima T, Umeno D, Saito K, Asai K and Sugo T. Removal of cesium using cobalt-ferrocyanide-impregnated polymer-chain-grafted fibers. J Nucl Sci Technol. 2011;48:1281-4.
[11] Kawatake K, Shigemoto N. Preparation of potassium iron(III) hexacyanoferrate(II) supported on activated carbon and Cs uptake performance of the adsorbent. J Nucl Sci Technol. 2012;49:1048-56.
[12] Takahashi A, Kitajima A, Parajuli D, Hakuta Y, Tanaka H, Ohkoshi S, Kawamoto T. radioactive cesium removal from ash-washing solution with high pH and high K+-concentration using potassium zinc hexacyanoferrate. Chem Eng Res Des. 2016;109:513-8.
[13] Hu B, Fugetsu B, Yu H, Abe Y. Prussian blue caged in spongiform adsorbents using diatomite and carbon nanotubes for elimination of cesium. J Hazard Mater. 2012;217-218:85-91.
[14] Yang H, Li H, Zhai J, Sun L, Zhao Y, Yu H. Magnetic Prussian blue/graphene oxide nanocomposites caged in calcium alginate microbeads for elimination of cesium ions from water and soil. Chem Eng J. 2014;246:10-9.
[15] Yang H, Jang S, Hong SB, Lee K, Roh C, Huh YS, Seo B, Prussian blue-functionalized magnetic nanoclusters for the removal of radioactive cesium from water. J Alloy Compd. 2016;657:387-93.
[16] Vincent C, Barré Y, Vincent T, Taulemesse J, Robitzer M, Guibal E. Chitin-Prussian blue sponges for Cs (I) recovery: from synthesis to application in the treatment of accidental dumping of metal-bearing solutions, J. Hazard. Mater. 2015;287:171-9.
[17] Dechojarassri D, Asaina S, Omote S, Nishida K, Furuike T, Tamura H. Adsorption and desorption behaviors of cesium on rayon fibers coated with chitosan immobilized with Prussian blue. Int J Biol Macromol. 2017;104:1509-16.
[18] Chen G, Chang Y, Liu X, Kawamoto T, Tanaka H, Kitajima A, Parajuli D, Takasaki M, Yoshino K, Chen M, Lo Y, Lei Z, Lee D. Prussian blue (PB) granules for cesium (Cs) removal from drinking water. Sep Purif Technol. 2015;143:146-51.
[19] Knorr D. Use of chitinous polymers in food—A challenge for good research and development. Food Technol-Chicago. 1984;38:85-97.
[20] Yang R, Su Y, Aubrecht KB, Wang X, Ma H, Grubbs RB, Hsiao BS, Chu B. Thiol-functionalized chitin nanofibers for As (III) adsorption. Polymer. 2015;60:9-17.
[21] Labidi A, Salaberria AM, Fernandes SCM, Labidi J, Abderrabbaa M. Adsorption of copper on chitin-based materials: kinetic and thermodynamic studies. J Taiwan Inst Chem E. 2016;65:140-8.
[22] Wawrzkiewicz M, Bartczak P, Jesionowski T. Enhanced removal of hazardous dye form aqueous solutions and real textile wastewater using bifunctional chitin/lignin biosorbent. Int J Biol Macromol. 2017;99:754-64.
[23] Kauffman GB. Rayon: The first semi-synthetic fiber product. J Chem Educ. 1993;70:887-93.
[24] Brinsko KM. Sparenga S, King M. The effects of environmental exposure on the optical, physical, and chemical properties of manufactured fibers of natural origin. J Forest Econ. 2016;61:1215-27.
[25] Vagholkar PK. Nylon (Chemistry, Properties and Uses). Int J Recent Sci Res. 2016;5:349-51.
[26] Guivar JAR, Sanches EA, Bruns F, Sadrollahi E, Morales MA, López EO, Litterst FJ. Vacancy ordered gamma-Fe2O3 nanoparticles functionalized with nanohydroxyapatite: XRD, FTIR, TEM, XPS and Mössbauer studies. Appl Surf Sci. 2016;389:721-34.
[27] Liu H, Wei G, Xu Z, Liu P, Li Y. Quantitative analysis of Fe and Co in co-substituted magnetite using XPS: The application of non-linear least squares fitting (NLLSF). Appl Surf Sci. 2016;389:438-46.
[28] Arun T, Prakash K, Kuppusamy R, Justin Joseyphus R. Magnetic properties of Prussian blue modified Fe3O4 nanocubes. J Phys Chem Solids. 2013;74:1761-8.
[29] Akhtar F, Podder J. A study on growth, structural, optical and electrical characterization of L-alanine single crystal for optoelectronic devices. Res J Phys. 2012;6:31-40.
[30] Shan Y, Yang G, Gong J, Zhang X, Zhu L, Qu L. Prussian blue nanoparticles potentiostatically electrodeposited on indium tin oxide/chitosan nanofibers electrode and their electrocatalysis towards hydrogen peroxide. Electrochim Acta. 2008;53: 7751-5.