Study on Viscosity and Acid of Lubricant-Water Contamination using Nano-Graphite Powder and Sunflower Oil as Additives

Authors

  • Puttha Jeenkour Department of Mechanical Engineering, Faculty of Engineering, Burapha University
  • Aphatsara Meephua Department of Mechanical Engineering, Faculty of Engineering, Burapha University
  • Satris Tabtimthong Department of Mechanical Engineering, Faculty of Engineering, Burapha University

Keywords:

Lubrication, oxidation reaction, nano-graphite, sunflower oil, viscosity, acid-base

Abstract

This paper studies the viscosities and acid levels of the lubricant-water contamination by using the additives. The increase in both the viscosity and acid in lubricating oil are significant factors contributing to the reduced efficiency of oil. Therefore, maintaining the oil properties has become the main issue and importance. The serious parameter that affects the oil properties is water contamination. Therefore, this article examines the oil properties that are contaminated with 1-5 % water by weight and added 1-5% additives by weight. The additives used include nano graphite powder and sunflower oil. The viscosities of the lubricant samples at different temperatures are measured using a dynamic viscometer. The acid levels are measured using a digital PH test kit, and the microscope enlarges the physical characteristics of the mixtures of the studied lubricants. The results show that adding the nano-graphite powder to a base oil with water contamination can maintain the viscosity and PH level better than the sunflower oil as an additive compared to a base oil without water contamination. Therefore, the use of nano-graphite powders is promising for use as an additive to prevent the effects of water contamination.

References

A. Y. El-Naggar, R. A. El-Adly, T. A. Altalhi, A. Alhadhrami, F. Modather, M. A. Ebiadb and A. Salemb, “Oxidation stability of lubricating base oils,” Petroleum Science and Technology, vol. 36, no. 3, pp. 179–185, 2018, doi: 10.1080/10916466.2017.1403450.

C. Georgescu, L. Deleanu and G. C. Cristea, “Tribological Behavior of Soybean Oil,” in Soybean - Biomass, Yield and Productivity, London, United Kingdom: IntechOpen, 2018, ch. 5, pp. 1–36. [Online]. Available: https://www.intechopen.com/chapters/64105, doi: 10.5772/intechopen.81234

J. K. Mannekote and S. V. Kailas, “The Effect of Oxidation on the Tribological Performance of Few Vegetable Oils,” Journal of Materials Research and Technology, vol.1, no. 2, pp.91–95, 2012, doi: 10.1016/S2238-7854(12)70017-0.

N. Canter, “Tribology & Lubrication Technology,” Society of Tribologists and Lubrication Engineers, Park Ridge, IL, USA, Special report use of antioxidants in automotive lubricants, 2008.

G. Karmakar and P. Ghosh, “Green Additives for Lubricating Oil,” ACS Sustainable Chemistry & Engineering, vol. 11, no. 1, pp. 1364–1370, 2013, doi: 10.1021/sc400181g.

M. A. Maleque, H. H. Masjuki and S. M. Sapuan, “Vegetable-based biodegradable lubricating oil additives,” Industrial Lubrication and Tribology,” vol. 55, pp. 137–143, 2003, doi: 10.1108/00368790310470976.

P. Ghosh, T. Das, D. Nandi, G. Karmakar and A. Mandal, “Synthesis and Characterization of Biodegradable Polymer – Used as a Pour Point Depressant for Lubricating Oil,” International Journal of Polymeric Materials, vol. 59, no. 12 pp. 1008-1017, 2010, doi: 10.1080/00914037.2010.504156.

E. Durak and F. Karaosmanoğlu, “Using of Cottonseed Oil as An Environmentally Accepted Lubricant Additive,” Energy Sources, vol. 26, no. 7, pp. 611–625, 2004, doi: 10.1080/00908310490438605.

S. B. Mousavi, S. Z. Heris and P. Estellé, “Experimental comparison between ZnO and MoS2 nanoparticles as additives on performance of diesel oil-based nano lubricant,” Scientific Reports, vol. 10, no. 1, 2020, Art. no. 5813, doi: 10.1038/s41598-020-62830-1.

H. Wu, J. Zhao, W. Xia, X. Cheng, A. He, J. Yun, L. Wang, H. Huang, S. Jiao, L. Huang, et al., “A study of the tribological behaviour of TiO2 nano-additive water-based lubricants,” Tribology International, vol. 109, pp. 398–408, 2017, doi: 10.1016/j.triboint.2017.01.013.

A. Beheshti, Y. Huang, K. Ohno, I. Blakey and J. R. Stokes, “Improving tribological properties of oil-based lubricants using hybrid colloidal additives,” Tribology International, vol. 144, 2020, Art. no. 106130, doi: 10.1016/j.triboint.2019.106130.

H. T. Nguyen and K. H. Chung, “Assessment of Tribological Properties of Ti3C2 as a Water-Based Lubricant Additive,” Materials, vol. 13, no. 23, 2020, Art. no. 5545, doi: 10.3390/ma13235545.

G. Cristea, D. Cazamir, D. Dima, C. Georgescu and L. Deleanu, “Influence of TiO2 as nano additive in rapeseed oil,” IOP Conference Series: Materials Science and Engineering, vol. 444, no. 2, 2018, Art. no. 022011, doi: 10.1088/1757-899X/444/2/022011.

S. D. Fernández-Silva, M. A. Delgado, C. Roman and M. García-Morales, “Rheological and Tribological Properties of Nanocellulose-Based Ecolubricants,” Nanomaterials (Basel), vol. 11, no. 11, pp. 1–14, 2021, Art. no. 34835751, doi: 10.3390/nano11112987.

M. Niu and J. Qu, “Tribological properties of nano-graphite as an additive in mixed oil-based titanium complex grease,” The royal society of chemistry, vol. 8, pp. 42133–42144, 2018, doi: 10.1039/c8ra08109c.

E. Omrani, A. Siddaiah, A. D. Moghadam, U. Garg, P. Rohatgi and P. L. Menezes, “Ball milled graphene nano additives for enhancing sliding contact in vegetable oil,” nanomaterials, vol.11, no. 3, 2021, Art. no. 610, doi: 10.3390/nano11030610.

G. C. Cristea, A. Radulescu, C. Georgescu, I. Radulescu and L. Deleanu, “Influence of additive concentration in soybean oil on rheological and tribological behavior,” in International conference of aerospace sciences “AEROSPATIAL2018”, Romania, 2018, pp. 35–43, doi: 10.13111/2066-8201.2018.10.4.4.

L. Kirkhorn, O. Gutnichenko, O. Melnyk, V. Bushlya and J. E. Stahl, “Nano graphite flakes as lubricant additive,” in Proc.of the 6th Swedish production symposium, Gothenburg, Sweden, 2014, pp.1–7.

P. S. Owuor, A. Khan, C. L. Leon, S. Ozden, R. Priestley, C. Arnold, N. Chopra and C. S. Tiwary, “Roadblocks faced by graphene in replacing graphite in large-scale applications,” Oxford open materials science, vol. 1, no. 1, pp.1–19, 2021, doi: 10.1093/oxfmat/itab004.

Safety Data Sheet Mobilux EP0 grease, ExxonMobil, Apr. 24, 2022. [Online]. Available: https://www.msds.exxonmobil.com/IntApps/psims/Download.aspx?ID=743086.

V. Cortes, K. Sanchez, R. Gonzalez, M. Alcoutlabi and J. A. Ortega, “The performance of SiO2 and TiO2 nanoparticles as lubricant additives in sunflower oil,” Lubricants, vol.8, no. 1, pp. 1–13, 2020, doi: 10.3390/lubricants8010010.

A. Sarwar, S. Vunguturi and A. Ferdose, “A study on smoke point and peroxide values of different widely used edible oils,” International journal of engineering technology science and research, vol. 3, no. 5, pp. 271–273, 2016.

J. Ashrafi, A. Semnani, H. S. Langeroodi and M. Shirani, “Direct acetylation of sunflower oil in the presence of boron trioxide catalyst and the adduct usage as the base stock and lubricant additive,” Bulletin of the Chemical Society of Ethiopia, vol. 31, no. 1, pp.39–49, 2017, doi: 10.4314/bcse.v31i1.4.

Graphite nanoparticles/nanopowder, American Elements, Jun.15, 2022. [Online]. Available: https://www.americanelements.com/graphite-nanoparticles-nanopowder-7782-42-5

B. J. Hamrock, S. R. Schmid and B. O. Jacobson, “Lubricant Properties,” in Fundamentals of fluid film lubrication, 2nd ed.,Boca Raton, NM, USA: CRC Press, 2004, ch. 4, sec. 4.17, pp. 122–123.

D. Choi, S. Yun and W. Choi, “An exact solution for power-law fluids in a slit microchannel with different zeta potentials under electroosmotic forces,” Micromachines (Basel), vol. 9, no. 10, 2018, Art. no. 504, doi: 10.3390/mi9100504.

M. Soleimani, L. Dehabadi, L. D. Wilson and L. G. Tabil, “Antioxidants Classification and Applications in Lubricants,” in Lubrication - Tribology, Lubricants and Additives, London, United Kingdom: IntechOpen, 2018, ch. 2, pp. 23–42 [Online]. Available: https://www.intechopen.com/chapters/58293.

S. Yotsawimonwat, S. Okonoki, K. Krauel, J. Sirithunyalug, B. Sirithunyalur and T. Rades, “Charaterisation of microemulsions containing orange oil with water and propylene glycol as hydrophilic components,” Pharmazie, vol.61, no. 11, pp. 920–926, 2006.

O. Juntarasakul and K. Maneeintr, “Evaluation of stability and viscosity measurement of emulsion from oil from production in northern oilfield in Thailand,” Iop conference series: Earth and environmental science, vol. 140, 2018, Art. no. 012024, doi: 10.1088/1755-1315/140/1/012024.

D. S. Kolotova, Y. A. Kuchina, L. A. Petrova, N. G. Voron,ko and S. R. Derkach, “Rheology of water-in-crude oil emulsions: influence of concentration and temperature,” colloids and interfaces, vol. 2, no. 4, 2018, Art. no. 64, doi: 10.3390/colloids2040064.

P. Madhaven and N. C. Werner, “Contamination Control for Extending Fluid Service Life.” machinerylubrication.com. https://www.machinerylubrication.com/Read/714/extending-fluid-life (accessed: Jun.10, 2022).

J. Wen, J. Zhang and M. Wei, “Effective viscosity prediction of crude oil-water mixtures with high water fraction,” Journal of petroleum science and engineering, vol. 147, pp.760–770, 2016, doi: 10.1016/j.petrol.2016.09.052.

Downloads

Published

2022-09-29

How to Cite

[1]
P. Jeenkour, A. . Meephua, and S. Tabtimthong, “Study on Viscosity and Acid of Lubricant-Water Contamination using Nano-Graphite Powder and Sunflower Oil as Additives”, Eng. & Technol. Horiz., vol. 39, no. 3, pp. 57–71, Sep. 2022.

Issue

Section

Research Articles