Effects of defect density on the FIR radiation spectra of anatase TiO2 powder
Keywords:
Far-infrared radiation, Energy level, DV-X, TiO2, Electron statesAbstract
Anatase TiO2 powder shows an excellent emissivity of 0.916 over the wavelength range of 7–20 µm at 250°C; however, it shows a relatively low emissivity of 0.767 over the range of 3–7 µm. We investigated the effect of structural defects on the radiation properties of anatase TiO2 powder by introducing point and line defects into the system. The emissivity over the range of 3–7 µm increased from 0.767 to 0.902 upon the introduction of appropriate quantities of oxygen vacancies. This result suggested that the radiation properties are related in part to electronic transitions and could be significantly improved by optimizing the crystallinity of the host material. The results from X-ray diffraction (XRD), Fourier-transform infrared spectrometer (FT-IR), and Raman spectroscopy were used to explain the observations, along with predictions by a discrete variational X-α (DV-Xa)molecular orbital simulation.
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