Adsorption of Organic Substance and Dyestuff from Batik Textiles Wastewater by Rubber Wood Fly Ash
DOI: 10.14416/j.ind.tech.2021.02.001
Keywords:
Fly ash, Adsorption, Batik wastewater, COD, DyestuffAbstract
This research has studied the utilization of rubber wood fly ash for batik textiles wastewater treatment at 5-8 of pH value, 75-300 µm of fly ash size, 2-24 hours of contact time and 5-50 g/L of fly ash dose which effected on the adsorption efficiency of COD and dyestuff removal. The batch experiment results showed that the adsorption efficiency of COD and dyestuff removal was about 96 % and 98 % at the optimum conditions, pH 7, the total size of fly ash (no sieve) with 8.02 nm of average pore size and 65.03 m2/g of average surface area, 16 hours of contact time and 100 g/L of fly ash dose. The organic adsorption in term of COD by rubber wood fly ash was analyzed and fitted with Freundlich isotherm under R2 0.8828. This result correlated with the linear physical adsorption characteristic on the surface area of fly ash at value of 1.0365.
References
[1] M.F. Siddiqui, Z.A. Wahid and M. Sakinah, Bioremediation and biofouling perspective of real batik effluent by indigenous bacteria, International Journal of Chemical and Environmental Engineering, 2011, 2(5), 302-308.
[2] W. Pimpa and C. Pimpa, Synthesis and utilization of the rice straw based adsorbents for wastewater treatment, Research Report of Agriculture, Naresuan University, 2014. (in Thai)
[3] M. Visa, L. Isac and A. Duta, Fly ash adsorbents for multi-cation wastewater treatment, Applied Surface Science, 2012, 258(17), 6345-6352.
[4] G. Patra, R. Barnwal, S.K. Behera and B.C. Meikap, Removal of dyes from aqueous solution by sorption with fly ash using a hydrocyclone, Journal of Environmental Chemical Engineering, 2018, 6(4), 5204-5211.
[5] K.E. Chingono, E. Sanganyado, E. Bere and B. Yalala, Adsorption of sugarcane vinasse effluent on bagasse fly ash: A parametric and kinetic study, Journal of Environmental Management, 2018, 224, 182-190.
[6] Rubber Intelligence Unit, Block from Para Rubber Wood Fly Ash, Available: http://www. rubber.oie.go.th/File/10_อิฐจากเถ้าลอยไม้ยางพารา.pdf (in Thai)
[7] A. Hawa, Properties of pumice lightweight concrete containing rubber wood fly ash and rice husk ash, Master Thesis of Engineering in Civil Engineering, Prince of Songkla University, Thailand. 2008.
[8] E.W. Rice, R.B. Baird, A.D. Eaton, Standard Method for the Examination of Water and Wastewater, 23rd Ed., American Public Health Association, American Water Works Association, Water Environment Federation, Washington D.C., USA, 2017.
[9] M. Visa, L. Andronic and A. Duta, Fly ash - TiO2 nanocomposite material for multi - pollutants wastewater treatment, Journal of Environmental Management, 2015, 150, 336-343.
[10] W. Kitchainukul, Adsorption of mercury contaminated synthetic water by fly ash from coal fired power plant, Bulletin of Applied Science, 2013, 2(2), 35-39.
[11] I. Langmuir, The adsorption of gases on plane surfaces of glass, mica and platinum, Journal of the American Chemical Society, 1918, 40, 1361-1403.
[12] H.M.F. Freundlich, Over the adsorption in solution, The Journal of Physical Chemistry, 1906, 57, 385-470.
[13] Ministry of industry, Industrial Effluent Standards,Available:https://www.diw.go.th/hawk/news/11.PDF, 18 December 2019. (in Thai)
[14] R. Srimoon, Dyes treatment in wastewater using adsorption processes, KKU Science Journal, 2016, 44(3), 419-434. (in Thai)
[15] B.A. Bekele, M.A Balcha, Ayalew and F.B. Demelash, Adsorption of methyl red on coal fly ash from aqueous solution, Chemistry and Materials Research, 2018, 10(4), 13-19.
[16] C.H. Maeda, C.A. Araki, A.L. Moretti, M.A.S.D. De Barros and P.A. Arroyo, Adsorption and desorption cycles of reactive blue dye BF-5G dye in a bone char fixed-bed column, Environmental Science and Pollution Research, 2019, 26, 28500-28509.
[17] R.M. Razanajatovo, J. Ding, S. Zhang, H. Jiang and H. Zou, Sorption and desorption of selected pharmaceuticals by polyethylene microplastics, Marine Pollution Bulletin, 2018, 136, 516-523.
[18] C. Zaharia and D. Suteu, Coal fly ash as adsorptive material for treatment of a real textile effluent: operating parameters and treatment efficiency, Environmental Science and Pollution Research, 2013, 20: 2226 -2235.
[19] V. Lalani and S.M. Usman, A study on removal of pollutants using fly ash adsorbent from dyes wastewater, Journal of Emerging Technologies and Innovative Research, 2020, 7(5), 417-422
[20] N.A.B. Rohaizar, N.B.A. Hadi and W.C. Sien, Removal of Cu (II) from water by adsorption on chicken eggshell, International Journal of Engineering & Technology, 2013, 13(1), 40-45.
[21] I. Boonyuen, Adsorption of lignin and tannin by wasted activated carbon used as ballasting agent from activated sludge process, Master Thesis of Engineering Program in Environmental Engineering, Chulalongkorn University, Thailand. 2009. (in Thai)
[2] W. Pimpa and C. Pimpa, Synthesis and utilization of the rice straw based adsorbents for wastewater treatment, Research Report of Agriculture, Naresuan University, 2014. (in Thai)
[3] M. Visa, L. Isac and A. Duta, Fly ash adsorbents for multi-cation wastewater treatment, Applied Surface Science, 2012, 258(17), 6345-6352.
[4] G. Patra, R. Barnwal, S.K. Behera and B.C. Meikap, Removal of dyes from aqueous solution by sorption with fly ash using a hydrocyclone, Journal of Environmental Chemical Engineering, 2018, 6(4), 5204-5211.
[5] K.E. Chingono, E. Sanganyado, E. Bere and B. Yalala, Adsorption of sugarcane vinasse effluent on bagasse fly ash: A parametric and kinetic study, Journal of Environmental Management, 2018, 224, 182-190.
[6] Rubber Intelligence Unit, Block from Para Rubber Wood Fly Ash, Available: http://www. rubber.oie.go.th/File/10_อิฐจากเถ้าลอยไม้ยางพารา.pdf (in Thai)
[7] A. Hawa, Properties of pumice lightweight concrete containing rubber wood fly ash and rice husk ash, Master Thesis of Engineering in Civil Engineering, Prince of Songkla University, Thailand. 2008.
[8] E.W. Rice, R.B. Baird, A.D. Eaton, Standard Method for the Examination of Water and Wastewater, 23rd Ed., American Public Health Association, American Water Works Association, Water Environment Federation, Washington D.C., USA, 2017.
[9] M. Visa, L. Andronic and A. Duta, Fly ash - TiO2 nanocomposite material for multi - pollutants wastewater treatment, Journal of Environmental Management, 2015, 150, 336-343.
[10] W. Kitchainukul, Adsorption of mercury contaminated synthetic water by fly ash from coal fired power plant, Bulletin of Applied Science, 2013, 2(2), 35-39.
[11] I. Langmuir, The adsorption of gases on plane surfaces of glass, mica and platinum, Journal of the American Chemical Society, 1918, 40, 1361-1403.
[12] H.M.F. Freundlich, Over the adsorption in solution, The Journal of Physical Chemistry, 1906, 57, 385-470.
[13] Ministry of industry, Industrial Effluent Standards,Available:https://www.diw.go.th/hawk/news/11.PDF, 18 December 2019. (in Thai)
[14] R. Srimoon, Dyes treatment in wastewater using adsorption processes, KKU Science Journal, 2016, 44(3), 419-434. (in Thai)
[15] B.A. Bekele, M.A Balcha, Ayalew and F.B. Demelash, Adsorption of methyl red on coal fly ash from aqueous solution, Chemistry and Materials Research, 2018, 10(4), 13-19.
[16] C.H. Maeda, C.A. Araki, A.L. Moretti, M.A.S.D. De Barros and P.A. Arroyo, Adsorption and desorption cycles of reactive blue dye BF-5G dye in a bone char fixed-bed column, Environmental Science and Pollution Research, 2019, 26, 28500-28509.
[17] R.M. Razanajatovo, J. Ding, S. Zhang, H. Jiang and H. Zou, Sorption and desorption of selected pharmaceuticals by polyethylene microplastics, Marine Pollution Bulletin, 2018, 136, 516-523.
[18] C. Zaharia and D. Suteu, Coal fly ash as adsorptive material for treatment of a real textile effluent: operating parameters and treatment efficiency, Environmental Science and Pollution Research, 2013, 20: 2226 -2235.
[19] V. Lalani and S.M. Usman, A study on removal of pollutants using fly ash adsorbent from dyes wastewater, Journal of Emerging Technologies and Innovative Research, 2020, 7(5), 417-422
[20] N.A.B. Rohaizar, N.B.A. Hadi and W.C. Sien, Removal of Cu (II) from water by adsorption on chicken eggshell, International Journal of Engineering & Technology, 2013, 13(1), 40-45.
[21] I. Boonyuen, Adsorption of lignin and tannin by wasted activated carbon used as ballasting agent from activated sludge process, Master Thesis of Engineering Program in Environmental Engineering, Chulalongkorn University, Thailand. 2009. (in Thai)
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Published
2021-02-04
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บทความวิจัย (Research article)
